Core-shell nanoparticle based SERS from hydrogen adsorbed on a rhodium(111) electrode.
Journal: Chemical Communications (Cambridge, England)
Published:
Abstract
We present the first in situ surface Raman spectra of hydrogen on rhodium under electrochemical conditions using gold-core rhodium-shell (Au@Rh) nanoparticles for SERS or gold-core silica-shell (Au@SiO(2)) nanoparticles for SHINERS. The advantage of SHINERS lies in the versatility to study single crystal surfaces such as the H-Rh(111) system.
Authors
Jian-feng Li, Jason Anema, Ying-chao Yu, Zhi-lin Yang, Yi-fan Huang, Xiao-shun Zhou, Bin Ren, Zhong-qun Tian