Preparation and reactivity of a dinitrogen-bridged dimolybdenum-tetrachloride complex.
Journal: Chemical Communications (Cambridge, England)
Published:
Abstract
A dinitrogen-bridged dimolybdenum-tetrachloride complex is prepared and reduced with Super-Hydride (LiBHEt3) to afford the corresponding dimolybdenum-dinitrogen complex together with the formation of molecular dihydrogen. This reaction proceeds via the ligand exchange of the coordinated dihydrogen generated in situ with molecular dinitrogen.
Authors
Kazuya Arashiba, Shogo Kuriyama, Kazunari Nakajima, Yoshiaki Nishibayashi