Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groups.
Journal: Chemical Communications (Cambridge, England)
Published:
Abstract
A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).
Authors
Takashi Toyao, Nana Ueno, Kenta Miyahara, Yasunori Matsui, Tae-ho Kim, Yu Horiuchi, Hiroshi Ikeda, Masaya Matsuoka