Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units.
Journal: Dalton Transactions (Cambridge, England : 2003)
Published:
Abstract
Complementarity of calixarene (H2L) and polyoxometalate ligands results in the first organic-inorganic [MIIIL{Mo5O13(OMe)4(NO)}]2- (M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO8 ligand field and resulting in slow relaxation of the magnetisation for the Dy derivative.
Authors
Yushu Jiao, Sergio Sanz, Natalya Izarova, Jan Van Leusen, Sidra Sarwar, Scott Dalgarno, Euan Brechin, Paul Kögerler