Deaminative defluoroalkylation of α-trifluoromethylalkenes enabled by photoredox catalysis.

Herein, we disclose a new photoredox-catalysed strategy to access gem-difluoroallylarenes from α-trifluoromethylalkenes with sterically hindered primary amines via C-N and C-F bond activation. This deaminative and defluorinative allylation is generally compatible with diverse functional groups and sterically hindered α-3° and 2° primary amines.