Ball-milled Ni@Mo2C/C nanocomposites as efficient electrocatalysts for urea oxidation.

Urea oxidation reaction (UOR) has been identified as a promising method for hydrogen production and the remediation of urea-rich wastewater by electrochemical techniques. In the present work, Ni/C and Ni@Mo2C(x)/C electrocatalysts (x = 0.1, 0.2, 0.4, and 0.6 mol fraction of Mo2C in Ni@Mo2C) are prepared by ball milling method followed by annealing at 800 °C for 2 h under nitrogen atmosphere. Electrooxidation of urea is carried out using these electrocatalysts in an alkaline solution. Among them, the Ni@Mo2C(0.4)/C catalyst shows a maximum current density of 96.5 mA cm-2 at 1.7 V (versus RHE) in 1 M KOH and 0.33 M urea electrolyte. The Ni@Mo2C(0.4)/C catalyst exhibits better catalytic activity, low overpotential, and charge transfer resistance with extremely low Tafel slope compared to other compositions for UOR. The synergistic electronic effect between Ni and Mo2C components is responsible for generating active sites and facilitating the catalytic activity of UOR. The Ni@Mo2C(x)/C electrocatalysts are promising for treating urea-rich wastewaters and for use as a substitute for suppressing OER in water-splitting reactions.