Application of iron-modified biochar in the fields of adsorption and degradation of antibiotics.

Antibiotics, as emerging contaminants, have led to persistent global pollution issues, prompting long-standing attention on methods for their effective removal. Among various methods, iron-modified biochar stood out for its ability to adsorb and degrade antibiotics in the environment because biochar can provide a porous structure and oxygen-rich functional groups for efficient antibiotic adsorption, while the Fe2+/Fe3+ redox cycle in the iron modification biochar enhanced electronic transmission and further increased degradation. This review systematically summarized preparation methods of different iron-modified biochar, the adsorption capacities, mechanisms, and influencing factors of pollutants. It also explored the co-activation of iron and biochar, which enhanced the release of free radicals through Fenton-like oxidation pathways and accelerated degradation through photocatalytic electron-hole pair production. Additionally, the relationship between adsorption and degradation was discussed. Notably, an environmental risk assessment of iron-modified biochar and disposal of the used iron-modified biochar were discussed, which were critical for practical applications. Finally, the review highlighted the future directions of antibiotic pollution control and the broader potential of iron-modified biochar.