A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s.
Journal: Chemical Communications (Cambridge, England)
Published:
Abstract
A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.
Authors
Hideyuki Otsuka, Koichiro Aotani, Yuji Higaki, Atsushi Takahara